乙硫醇

中文名称:乙硫醇

英文名称:EthanethiolCAS号:75-08-1分子式:C2H6S分子量:62.13EINECS号:200-837-3

属性

熔点 -148 °C沸点 35 °C(lit.)
密度 0.839 g/mL at 25 °C(lit.)
蒸气密度2.1 (vs air)
蒸气压8.51 psi ( 20 °C)
折射率 n20/D 1.4306(lit.)
FEMA 4258 | ETHANETHIOL闪点 1 °F
储存条件 2-8°C溶解度 6.8g/l酸度系数(pKa)10.6(at 25℃)形态Liquid颜色Colorless气味 (Odor)Strong chunk; offensive garlic.气味 (Odor)Ethanethiol has a strongly disagreeable odor that humans can detect in minute concentrations. The threshold for human detection is as low as one part in 2.8 billion parts of air. Its odor resembles that of leeks, onions or cooked cabbage, but is quite distinct. Ethanethiol is intentionally added to butane and propane (see: LPG) to impart an easily noticed smell to these normally odorless fuels that pose the threat of fire, explosion, and asphyxiation.爆炸极限值(explosive limit)2.8-18%(V)水溶解性 Soluble in alcohol, ether, waterMiscible with alcohol, petroleum naphtha, acetone, dilute alkali and ether. Slightly miscible with water.JECFA Number1659Merck 14,3726BRN 773638暴露限值TLV-TWA 0.5 ppm (~1.3 mg/m3 ) (ACGIH and MSHA); ceiling 10 ppm (OSHA); IDLH 2500 ppm (NIOSH).稳定性Stable. Extremely flammable - note low flash point. Incompatible with oxidizing agents, strong acids. May form explosive mixtures with air.

安全信息

危险性符号(GHS)
GHS02,GHS07,GHS09,GHS08警示词Danger危险性描述H225-H332-H400-H224-H302+H332-H410-H319-H335-H370防范说明P280a-P304+P340-P501a-P233-P240-P241+P242+P243-P260-P264-P270-P271-P280-P303+P361+P353-P304+P340+P312-P305+P351+P338+P337+P313-P307+P311-P391-P403+P233-P405-P210-P273-P501-P261-P301+P312+P330-P370+P378-P403+P235危险品标志 F,Xn,N,F+危险类别码 11-20-50/53-51/53-12-20/22安全说明 16-25-60-61危险品运输编号 UN 2363 3/PG 1
WGK Germany 3
RTECS号KI9625000
13自燃温度570 °FTSCA Yes海关编码 2930 90 98HazardClass 3PackingGroup I毒性LD50 orally in Rabbit: 682 mg/kg